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Lookup NU author(s): Professor Michael North
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Chiral dinuclear titanium(IV) complexes (generated in situ from hexadentate Schiff bases and titanium tetra-isopropoxide) have been found to be more effective catalysts for the asymmetric addition of trimethylsilyl cyanide to aldehydes and the ring opening of cyclohexene oxide than their mononuclear analogues. The best results were obtained for benzaldehyde (86% enantiomeric excess) and cyclohexene oxide (89% enantiomeric excess). © 2006 Elsevier Ltd. All rights reserved.
Author(s): Belokon YN, Chusov D, Borkin DA, Yashkina LV, Dmitriev AV, Katayev D, North M
Publication type: Article
Publication status: Published
Journal: Tetrahedron: Asymmetry
ISSN (print): 0957-4166
ISSN (electronic): 1362-511X
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