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Post-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Sophie Dale, Dr Ross Harrington


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(Chemical Equation Presented) Catch me if you can: Invisible using standard electrophilic substitution detection methods, two distinct ortho-metalated "intermediates" generated by alkali-metal-mediated zincation of N,N-diisopropylbenzamide are structurally elucidated. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Publication metadata

Author(s): Clegg W, Dale SH, Harrington RW, Hevla E, Honeyman GW, Mulvey RE

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie International Edition

Year: 2006

Volume: 45

Issue: 15

Pages: 2374-2377

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA


DOI: 10.1002/anie.200503213


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