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Lookup NU author(s): Dr Sophie Dale,
Dr Mark Elsegood
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The crystal structure of dimeric μ-oxalato-bis[(η6-p- cymene)(triphenylphosphine)ruthenium(II)] bis(tetrafluoroborate), [Ru 2(C2O4)(C10H14) 2(C18H15P)2](BF4) 2, has the cation lying on an inversion centre. The complex demonstrates the trans bond-weakening influence, with the longest Ru-C(η6-p-cymene) bonds in the complex lying trans to the phosphine group. The related mononuclear species (η6-p-cymene) (oxalato)(pyridine-3,5-dicarboxylic acid)ruthenium(II), [Ru(C2O 4)(C10H14)(C7H5NO 4)], crystallizes as hydrogen-bonded tapes linked through O-H⋯O hydrogen bonds. © 2006 International Union of Crystallography.
Author(s): Dale SH, Elsegood MRJ
Publication type: Article
Publication status: Published
Journal: Acta Crystallographica Section C: Crystal Structure Communications
ISSN (print): 0108-2701
ISSN (electronic): 1600-5759
Publisher: Wiley-Blackwell Publishing, Inc.
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