Toggle Main Menu Toggle Search

Open Access padlockePrints

Catalytic, asymmetric Strecker reactions catalysed by titaniumIV and vanadiumV(salen) complexes

Lookup NU author(s): Lisa Clutterbuck, Dr Christophe Grosjean, Professor Michael North

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

VanadiumV(salen) complex 3 has been found to be an effective catalyst for the asymmetric addition of hydrogen cyanide (generated in situ from trimethylsilyl cyanide) to imines. The best results (up to 81% enantiomeric excess) were obtained for aromatic imines in which the nitrogen atom is protected with a benzyl group and in which the imine bond is not sterically encumbered. © 2006 Elsevier Ltd. All rights reserved.


Publication metadata

Author(s): Blacker J, Clutterbuck LA, Crampton MR, Grosjean C, North M

Publication type: Article

Publication status: Published

Journal: Tetrahedron: Asymmetry

Year: 2006

Volume: 17

Issue: 9

Pages: 1449-1456

ISSN (print): 0957-4166

ISSN (electronic): 1362-511X

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/j.tetasy.2006.05.015

DOI: 10.1016/j.tetasy.2006.05.015


Altmetrics

Altmetrics provided by Altmetric


Share