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Lookup NU author(s): Lisa Clutterbuck,
Dr Christophe Grosjean,
Professor Michael North
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VanadiumV(salen) complex 3 has been found to be an effective catalyst for the asymmetric addition of hydrogen cyanide (generated in situ from trimethylsilyl cyanide) to imines. The best results (up to 81% enantiomeric excess) were obtained for aromatic imines in which the nitrogen atom is protected with a benzyl group and in which the imine bond is not sterically encumbered. © 2006 Elsevier Ltd. All rights reserved.
Author(s): Blacker J, Clutterbuck LA, Crampton MR, Grosjean C, North M
Publication type: Article
Publication status: Published
Journal: Tetrahedron: Asymmetry
ISSN (print): 0957-4166
ISSN (electronic): 1362-511X
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