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Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(η5-C5Me5)} 2]. Synchrotron X-ray structures of [(η5-C 5Me5)2Ir2B16H 17Cl]

Lookup NU author(s): Emeritus Professor Bill Clegg

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Abstract

Products from the reaction of + nido ten-vertex: nido eight-vertex, B 16H20 1 with [{(IrCl2(η5-C 5Me5)}2] and tmnd show unanticipated rearrangement of the starting {B16} skeleton, as exhibited by + nido ten-vertex: nido ten-vertex, [(η5-C5Me 5)2Ir2B16H17Cl] 2 which has a {B2} edge conjunction and by + nido ten-vertex: nido eleven-vertex, [(η5-C5Me5) 2Ir2B16H15Cl] 3 which has a {B 3} face conjunction. © The Royal Society of Chemistry 2006.


Publication metadata

Author(s): Carr MJ, Perera SD, Jelinek T, Kilner CA, Clegg W, Tibr B, Kennedy JD

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2006

Issue: 44

Pages: 5221-5224

Print publication date: 01/01/2006

Date deposited: 09/07/2010

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b611734a

DOI: 10.1039/b611734a


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