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Lookup NU author(s): Emeritus Professor Bill CleggORCiD,
Dr Sophie Dale
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(Figure Presented) Zinc twice: Naphthalene is attacked and doubly deprotonated at the 2,6-position by a synergic sodium zincate base to generate a centrosymmetric dizincated molecule. The approach of alkali-metal-mediated zincation can effect dimetalation as well as monometalation of polycyclic aromatic hydrocarbons, thus providing access to new zincated naphthalenes that are inaccessible directly through mainstream organozinc reagents. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Author(s): Clegg W, Dale SH, Hevia E, Hogg LM, Honeyman GW, Mulvey RE, O'Hara CT
Publication type: Article
Publication status: Published
Journal: Angewandte Chemie - International Edition
ISSN (print): 1433-7851
ISSN (electronic): 1521-3773
Publisher: Wiley - VCH Verlag GmbH & Co. KGaA
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