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Cationic terminal borylene complexes: Interconversion of amino and alkoxy borylenes by an unprecedented Meerwein-Ponndorf hydride transfer

Lookup NU author(s): Dr Ross Harrington, Emeritus Professor Bill Clegg

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Abstract

(Chemical Equation Presented) It's all new to B: In the reaction of borylene complex 1 with benzophenone, a Meerwein-Ponndorf β-hydride transfer from the aminoborylene ligand to the coordinated ketone generates 2 (see structure), the first example of an imine-donor-stabilized borylene complex, and the first cationic alkoxyborylene system. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.


Publication metadata

Author(s): Kays DL, Day JK, Aldridge S, Harrington RW, Clegg W

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie International Edition

Year: 2006

Volume: 45

Issue: 21

Pages: 3513-3516

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.200600714

DOI: 10.1002/anie.200600714


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