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Directed meta-metalation using alkali-metal-mediated zincation

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Sophie Dale

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Abstract

(Figure Presented) Move over directed ortho-metalation, here comes directed meto-metalation. The unprecedented meto-zincation of two anilides by a synergic mixed sodium/zinc dialkyl-amide base is presented. The orientation of the deprotonation of the anilides is remarkably switched to the meta site using this heterometallic mixed-metal system. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.


Publication metadata

Author(s): Armstrong DR, Clegg W, Dale SH, Hevia E, Hogg LM, Honeyman GW, Mulvey RE

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie International Edition

Year: 2006

Volume: 45

Issue: 23

Pages: 3775-3778

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.200600720

DOI: 10.1002/anie.200600720


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