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Lookup NU author(s): Professor William Clegg, Dr Sophie Dale
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(Figure Presented) Move over directed ortho-metalation, here comes directed meto-metalation. The unprecedented meto-zincation of two anilides by a synergic mixed sodium/zinc dialkyl-amide base is presented. The orientation of the deprotonation of the anilides is remarkably switched to the meta site using this heterometallic mixed-metal system. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Author(s): Armstrong DR, Clegg W, Dale SH, Hevia E, Hogg LM, Honeyman GW, Mulvey RE
Publication type: Article
Publication status: Published
Journal: Angewandte Chemie International Edition
Year: 2006
Volume: 45
Issue: 23
Pages: 3775-3778
ISSN (print): 1433-7851
ISSN (electronic): 1521-3773
Publisher: Wiley - VCH Verlag GmbH & Co. KGaA
URL: http://dx.doi.org/10.1002/anie.200600720
DOI: 10.1002/anie.200600720
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