Toggle Main Menu Toggle Search

Open Access padlockePrints

The Newcastle University research output collection, currently available on ePrints, will shortly be moving to a new open repository platform, Figshare. To prepare for the data migration we have paused adding new content to ePrints, and will resume once the new repository is launched. During this time you will continue to have access to ePrints (but no new content will appear). We will share updates here when available.

A tetraazamacrocycle with benzyl substituents

Lookup NU author(s): Professor Jong-Ha Choi, Professor William Clegg, Dr Ross Harrington

Downloads

Abstract

The molecule of the title compound, 2,13-dibenzyl-5,16-dimethyl-2,6,13,17-tetraazatricyclo[16.4.0 1,8.07,12]docosane, C34H52N 4, is centrosymmetric. The 14-membered macrocycle adopts the stable trans-III (RRSS) configuration, with one benzyl group above and the other below the macrocycle mean plane. The crystal structure is stabilized by N - H⋯N hydrogen bonds. There is no intermolecular π-π interaction between benzyl planes, which are almost 6Å apart. © 2006 International Union of Crystallography All rights reserved.

Publication metadata

Author(s): Choi J-H, Clegg W, Harrington RW, Yoon H-M, Hong YP

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2006

Volume: 62

Issue: 2

Pages: o644-o646

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1107/S1600536806001425

DOI: 10.1107/S1600536806001425

Altmetrics

Altmetrics provided by Altmetric

Share