Browse by author
Lookup NU author(s): Dr Sophie Dale
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
An isomeric series of six linear, dinuclear, gold(I) complexes (AuCl) 2{P,P-C6H4N(CH2PPh2) 2(CO2H)(OH)} 6a-6f have been synthesised in high yields (>90%) from AuCl(tht) (tht = tetrahydrothiophene) and the appropriate building blocks C6H4N(CH2PPh2) 2(CO2H)(OH) 3a-3f in CH2Cl2. The diphosphine ligands C6H4N(CH2PPh 2)2 1, 4-CO2HC6H 4N(CH2PPh2)2 2 and their corresponding digold(I) complexes 4 and 5 have also been prepared. Solution NMR (31P{1H}, 1H), FT-IR and microanalytical data are in full agreement with the proposed structures. Single crystal X-ray studies confirm that in each case, compounds 4, 5, 6a-6e are linear, with typical Au-P [2.227(4)-2.2349(17) Å]/Au-Cl [2.271(2)-2.325(4) Å] bond lengths and P-Au-Cl [169.37(1)-179.05(4)°] bond angles. Furthermore these studies demonstrate the relationship between regioselectivity, with respect to the -N(CH2PPh2)2, -CO2H and -OH functionalities around the benzene core, and solid state structures of the gold(I) complexes 6a-6e. In 6a, molecules are associated into pairs through classical intermolecular O-H⋯O hydrogen bonding, whilst in 6b and 6c, dimer pairs are formed using intermolecular O-H⋯;Cl hydrogen bonds. 1-D chains of alternate 20-/22- or 8-/18-membered hydrogen bonded rings are propagated using O-H⋯Cl and/or O-H⋯O hydrogen bonds in compounds 6d and 6e. The Au⋯Au separation decreases from 6.179(3) Å (for 6a) to 3.0722(9) Å (for 6e) suggesting that aurophilicity increases within this series. The X-ray structure of a representative diphosphine 3a is also presented. © The Royal Society of Chemistry 2006.
Author(s): Smith MB, Dale SH, Coles SJ, Gelbrich T, Hursthouse MB, Light ME
Publication type: Article
Publication status: Published
Journal: CrystEngComm
Year: 2006
Volume: 8
Issue: 2
Pages: 140-149
ISSN (electronic): 1466-8033
Publisher: Royal Society of Chemistry
URL: http://dx.doi.org/10.1039/b516023e
DOI: 10.1039/b516023e
Altmetrics provided by Altmetric