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Lookup NU author(s): Professor William Clegg, Dr Sophie Dale
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(Chemical Equation Presented) The predator meets its prey in the structure of [{(iPr)2NC(Ph) (=O)}Li(μ-tmp) (μ-tBu)Zn(tBu)] which reveals an aromatic amide-alkali metal zincate "precomplex" for directed ortho-metalation (DoM) that exists prior to the devouring (ortho-zincation) of the amide by the zincate. tmp = 2,2,6,6-tetramethylpiperidide. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Author(s): Clegg W, Dale SH, Hevia E, Honeyman GW, Mulvey RE
Publication type: Article
Publication status: Published
Journal: Angewandte Chemie International Edition
Year: 2006
Volume: 45
Issue: 15
Pages: 2370-2374
ISSN (print): 1433-7851
ISSN (electronic): 1521-3773
Publisher: Wiley - VCH Verlag GmbH & Co. KGaA
URL: http://dx.doi.org/10.1002/anie.200503202
DOI: 10.1002/anie.200503202
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