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Sodium-mediated manganation: Direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Luca Russo

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Abstract

Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6- tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.


Publication metadata

Author(s): Carrella LM, Clegg W, Graham DV, Hogg LM, Kennedy AR, Klett J, Mulvey RE, Rentschler E, Russo L

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie - International Edition

Year: 2007

Volume: 46

Issue: 25

Pages: 4662-4666

Print publication date: 01/01/2007

ISSN (print): 1433-7851

ISSN (electronic): 1521-3757

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1002/anie.200700965

DOI: 10.1002/anie.200700965


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