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Lookup NU author(s): Emeritus Professor Bill Clegg,
Dr Luca Russo
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Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6- tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
Author(s): Carrella LM, Clegg W, Graham DV, Hogg LM, Kennedy AR, Klett J, Mulvey RE, Rentschler E, Russo L
Publication type: Article
Publication status: Published
Journal: Angewandte Chemie - International Edition
Print publication date: 01/01/2007
ISSN (print): 1433-7851
ISSN (electronic): 1521-3757
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