Toggle Main Menu Toggle Search

Open Access padlockePrints

On the conjugation length for oligo(ethynylnaphthalene)-based molecular rods

Lookup NU author(s): Professor Andrew Benniston, Emeritus Professor Anthony Harriman, Dorota Rewinska, Dr Songjie Yang, Dr Yong-Gang Zhi


Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


The synthesis is described for a small series of oligomers built from (2, 3, 4 or 6) ethynyl-naphthalene repeat units and end-capped with solubilising 1,2,3-tris-dodecyloxy-benzene groups. These compounds absorb in the near-UV region and exhibit strong fluorescence in both fluid solution and a glassy matrix at 77 K. The spectral profiles are fully consistent with a structurally heterogeneous ground state becoming more planar upon excitation and with the low-temperature glass further stabilising the co-planar orientation. The absorption and fluorescence maxima move towards lower energy with increasing number of repeat units and there is a corresponding increase in the Huang-Rhys factor for the radiative process. The non-radiative rate constants also depend on molecular length and are well explained in terms of the energy-gap law. In contrast, very weak phosphorescence is observed at 77 K for which the peak maximum and lifetime remain insensitive to the number of naphthalene units. The triplet lifetimes recorded at ambient temperature are also independent of the molecular length but the triplet-triplet absorption spectra change throughout the series. These results are discussed in terms of the degree of electronic coupling between adjacent repeat units for each of the relevant excited states. During these studies it was noted that the rate of intersystem crossing to the triplet manifold is but weakly affected by heavy-atom perturbers. A non-fluorescent complex is formed between iodoethane and the molecular rod but the corresponding bimolecular process occurs at well below the diffusion-controlled limit. This behaviour is considered in terms of spin-orbit coupling between the excited states and takes account of the differing conjugation lengths. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

Publication metadata

Author(s): Benniston AC, Harriman A, Rewinska DB, Yang S, Zhi Y-G

Publication type: Article

Publication status: Published

Journal: Chemistry - A European Journal

Year: 2007

Volume: 13

Issue: 36

Pages: 10194-10203

Print publication date: 01/01/2007

ISSN (print): 0947-6539

ISSN (electronic): 1521-3765

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA


DOI: 10.1002/chem.200701235


Altmetrics provided by Altmetric