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Lookup NU author(s): Emeritus Professor Bill Clegg,
Dr Sophie Dale
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Benzene can be easily 1,4-dideprotonated stoichiometrically on reaction with two equivalents of a synergic mixture of tBu2Zn, NaTMP and TMEDA to give a unique 1,4-dizincated benzene product which has been characterised by X-ray crystallography and NMR spectroscopy as well as modelled theoretically by DFT computational studies; a related synergic dimagnesiation of benzene is also reported. © The Royal Society of Chemistry.
Author(s): Armstrong DR, Clegg W, Dale SH, Graham DV, Hevia E, Hogg LM, Honeyman GW, Kennedy AR, Mulvey RE
Publication type: Article
Publication status: Published
Journal: Chemical Communications
Print publication date: 01/01/2007
ISSN (print): 1359-7345
ISSN (electronic): 1364-548X
Publisher: Royal Society of Chemistry
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