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New coordination modes at molybdenum for 2-diphenylphosphinoaniline derived ligands

Lookup NU author(s): Dr Mark Elsegood, Professor William Clegg

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Abstract

The complexes [MoCl3(1-N,2-Ph2P-C6H 4)2] (1) and {MoCl(Nt-Bu)[1-μ(N),2-(Ph 2P)C6H4]}2 (2) have been obtained from the reaction of 2-diphenylphosphinoaniline [1,2-(NH2)(Ph 2P)C6H4] with either sodium molybdate [Na 2MoO4] (in the presence of Et3N and Me 3SiCl) or [MoCl2(Nt-Bu)2(DME)]; the crystal structure of 1 reveals a novel MoNC2PN six-membered conjugated ring system derived from a P-N coupling reaction between two ligands, whilst that of 2 reveals bridging imido/terminal phosphine ligation. © The Royal Society of Chemistry.

Publication metadata

Author(s): Redshaw C, Gibson VC, Elsegood MRJ, Clegg W

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2007

Issue: 19

Pages: 1951-1953

Print publication date: 01/01/2007

Date deposited: 05/07/2010

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b700158d

DOI: 10.1039/b700158d

PubMed id: 17695240

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