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Lookup NU author(s): Dr Mark Elsegood,
Emeritus Professor Bill Clegg
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The reactions of chelating diboranes with PhCMe2Cl and related initiators were studied by variabletemperature NMR spectroscopy. Although thermally stable ion-pairs featuring weakly coodinating anions (WCA) are formed, isobutene polymerization is complicated by the tendency of these WCA to act as hindered bases toward Brønsted acidic chain ends. © 2007 American Chemical Society.
Author(s): Chai J, Lewis SP, Collins S, Sciarone TJJ, Henderson LD, Chase PA, Irvine GJ, Piers WE, Elsegood MRJ, Clegg W
Publication type: Article
Publication status: Published
ISSN (print): 0276-7333
ISSN (electronic): 1520-6041
Publisher: American Chemical Society
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