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Formation of chelated counteranions using lewis acidic diboranes: Relevance to isobutene polymerization

Lookup NU author(s): Dr Mark Elsegood, Emeritus Professor Bill Clegg

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Abstract

The reactions of chelating diboranes with PhCMe2Cl and related initiators were studied by variabletemperature NMR spectroscopy. Although thermally stable ion-pairs featuring weakly coodinating anions (WCA) are formed, isobutene polymerization is complicated by the tendency of these WCA to act as hindered bases toward Br√łnsted acidic chain ends. ¬© 2007 American Chemical Society.


Publication metadata

Author(s): Chai J, Lewis SP, Collins S, Sciarone TJJ, Henderson LD, Chase PA, Irvine GJ, Piers WE, Elsegood MRJ, Clegg W

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 2007

Volume: 26

Issue: 23

Pages: 5667-5679

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om700672q

DOI: 10.1021/om700672q


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