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Macropolyhedral boron-containing cluster chemistry. The unique nido-five-vertex-〈B2〉-nido-ten-vertex conjuncto structure of [(η5-C5Me5)2Rh 2B11H15] via an unexpected cluster-dismantling

Lookup NU author(s): Emeritus Professor Bill Clegg

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Abstract

B16H20 and [RhCl2(η5-C 5Me5)]2 with tmnd give [(η5- C5Me5)2Rh2B11H 15], which has an unprecedented thirteen-vertex macropolyhedral cluster core based on a nido ten-vertex {MB9} subcluster and a nido five-vertex {MB4} subcluster fused with their open-face {B 2} edges in common. © The Royal Society of Chemistry.


Publication metadata

Author(s): Carr MJ, Perera SD, Jelinek T, Stibr B, Clegg W, Kilner CA, Kennedy JD

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2007

Issue: 34

Pages: 3559-3561

Print publication date: 01/01/2007

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b709470a

DOI: 10.1039/b709470a


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