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μ3-Iodido-tri-μ3-sulfido-tris- [(triphenylphosphine)silver(I)][thioxotungsten(VI)] dichloro-methane 0.45-solvate

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Sophie Dale

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Abstract

In the title complex, [WAg3IS4(C18H15P)3]·0.45CH2Cl2, the W atom has almost regular tetra-hedral coordination geometry, with one terminal and three triply bridging S atoms; the Ag atoms have tetra-hedral coordination geometry distorted by expanded P - Ag - S and contracted S - Ag - S angles, the fourth site being occupied by a triply bridging I atom. The bridging S and I atoms, together with the W and three Ag atoms, form a pseudo-cubane core with small angles at the non-metal vertices, resulting in short W⋯Ag distances. The dichloro-methane solvent mol-ecule is disordered over two inversion-related sites with common Cl-atom sites and with a refined occupancy factor of 0.449 (4) for each site. © International Union of Crystallography 2007.


Publication metadata

Author(s): Beheshti A, Clegg W, Dale SH, Hyvadi R

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2007

Volume: 63

Issue: 7

Pages: m1990-m1991

ISSN (print): 1600-5368

ISSN (electronic):

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1107/S1600536807030218

DOI: 10.1107/S1600536807030218


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