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Bis[chloridobis(triphenyl-phosphine)-copper(I)-μ-chlorido]bis-(1, 2-diamino-propane)copper(II) acetonitrile disolvate

Lookup NU author(s): Professor Mohammad Habibi, Dr Ross Harrington, Emeritus Professor Bill Clegg

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Abstract

The title complex [systematic name: bis-(1,2-diamino-propane-22 N,N′)di - chlorido-1:22 Cl,2:32 Cl-dichlorido-1Cl, 3Cl-tetra-kis(triphenyl-phosphine)-12 P,32 P-tricopper(I,II,I) acetonitrile disolvate], [{(Ph3P)2Cl2Cu}2Cu(C3H10N2)2] ·2C2H3N, is a centrosymmetric linear trinuclear mixed-valence copper complex in which the central CuII atom is bridged by Cl atoms to the two CuI atoms. The coordination geometry is octa-hedral for Cu II, with Jahn-Teller elongation of the Cu - Cl bonds, and distorted tetra-hedral for CuI, with a wide P - Cu - P angle. The diamine ligands are twofold disordered, with occupancy factors of ca 0.6:0.4, and form one N - H⋯Cl hydrogen bond each with a terminal Cl atom. © International Union of Crystallography 2007.


Publication metadata

Author(s): Habibi MH, Mikhak M, Harrington RW, Clegg W

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2007

Volume: 63

Issue: 9

Pages: m2305-m2306

ISSN (print): 1600-5368

ISSN (electronic):

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1107/S1600536807037282

DOI: 10.1107/S1600536807037282


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