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Lookup NU author(s): Professor Michael North
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Treatment of cis-4,5-diaminocyclohexene derivatives bearing allyl or propargyl groups on the nitrogen atoms, with first or second generation Grubbs metathesis catalysts, results in initiation of metathesis cascades which include ring-opening of the unstrained cyclohexene ring. This contrasts with the previous work on the analogous cyclohexene ethers where metathesis reactions occurred exclusively between the side-chains and no ring-opening of the cyclohexene unit was observed. © 2007 Elsevier Ltd. All rights reserved.
Author(s): Groaz E, Banti D, North M
Publication type: Article
Publication status: Published
Journal: Tetrahedron Letters
ISSN (print): 0040-4039
ISSN (electronic): 1873-3581
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