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Alkene and enyne metathesis reactions on allylic and propargylic amines

Lookup NU author(s): Professor Michael North

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Abstract

Treatment of cis-4,5-diaminocyclohexene derivatives bearing allyl or propargyl groups on the nitrogen atoms, with first or second generation Grubbs metathesis catalysts, results in initiation of metathesis cascades which include ring-opening of the unstrained cyclohexene ring. This contrasts with the previous work on the analogous cyclohexene ethers where metathesis reactions occurred exclusively between the side-chains and no ring-opening of the cyclohexene unit was observed. © 2007 Elsevier Ltd. All rights reserved.

Publication metadata

Author(s): Groaz E, Banti D, North M

Publication type: Article

Publication status: Published

Journal: Tetrahedron Letters

Year: 2007

Volume: 48

Issue: 11

Pages: 1927-1930

ISSN (print): 0040-4039

ISSN (electronic): 1873-3581

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/j.tetlet.2007.01.092

DOI: 10.1016/j.tetlet.2007.01.092

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