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Tetrakis(1,10-phenanthrolinium) hexa-chloridoeuropate(III) chloride

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Ross Harrington

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Abstract

In the title compound, (C12H9N)4[EuCl6]Cl, the EuIII atom has slightly distorted octa-hedral coordination. The longest Eu - Cl bond (Table 1) is to a Cl atom that serves as acceptor of a hydrogen bond from one of the four crystallographically independent singly-protonated 1,10-phenanthrolinium cations. The other three cations all form hydrogen bonds to the uncoordinated chloride anion, which is surrounded approximately in a trigonal plane by the three donors (Table 2). There is extensive π-stacking of the planar cations, with inter-planar distances in the range 3.3-3.7Å. © International Union of Crystallography 2007.


Publication metadata

Author(s): Clegg W, Harrington RW

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2007

Volume: 63

Issue: 4

ISSN (print): 1600-5368

ISSN (electronic):

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1107/S1600536807012329

DOI: 10.1107/S1600536807012329


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