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The Schiff base N,N′-bis-(3-nitrobenzylidene)propane-1,3-diamine

Lookup NU author(s): Professor Mohammad Habibi, Dr Ross Harrington, Emeritus Professor Bill Clegg

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Abstract

The mol-ecule of the title Schiff base compound, C17H16N4O4, has crystallographic twofold rotation symmetry. The nitro and CH=N - C substituents are coplanar with the benzene ring in each half of the mol-ecule. These two planar units are parallel, but extend in opposite directions from the central methyl-ene bridge, so there is no intra-molecular π-stacking. Instead, mol-ecules pack with approximately parallel inter-leaved benzene rings providing inter-molecular π-stacking, the centroid-to-centroid separation being 3.7196 (18) Å. © International Union of Crystallography 2007.


Publication metadata

Author(s): Habibi MH, Mokhtari R, Harrington RW, Clegg W

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2007

Volume: 63

Issue: 6

ISSN (print): 1600-5368

ISSN (electronic):

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1107/S1600536807021940

DOI: 10.1107/S1600536807021940


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