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Structurally Defined Reactions of Sodium TMP–Zincate with Nitrile Compounds: Synthesis of a Salt-Like Sodium Sodiumdizincate and Other Unexpected Ion-Pair Products

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Sophie Dale, Dr Luca Russo

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Abstract

Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes. (Chemical Equation Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.


Publication metadata

Author(s): Clegg W, Dale SH, Hevia E, Hogg LM, Honeyman GW, Mulvey RE, O'Hara CT, Russo L

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie: International Edition

Year: 2008

Volume: 47

Issue: 4

Pages: 731-734

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.200704341

DOI: 10.1002/anie.200704341


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