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Synthesis of N-heterocyclic compounds via ene-yne metathesis reactions

Lookup NU author(s): Professor Michael North

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Abstract

Propargylamino and allylamino derivatives of cyclohexene and norbornene were subjected to tandem metathesis reactions with first and second generation Grubbs' catalysts 1 and 2. Results show that the method is compatible with suitably protected nitrogen-containing compounds. Cyclohexenes gave intriguing results in terms of the possibility to perform ring rearrangement metathesis (RRM) reactions, showing a difference with the analogous allyl and propargyl ether substrates. © 2007 Elsevier Ltd. All rights reserved.

Publication metadata

Author(s): Groaz E, Banti D, North M

Publication type: Article

Publication status: Published

Journal: Tetrahedron

Year: 2008

Volume: 64

Issue: 1

Pages: 204-218

ISSN (print): 0040-4020

ISSN (electronic): 1464-5416

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/j.tet.2007.10.076

DOI: 10.1016/j.tet.2007.10.076

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