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Product identification and distribution from the oscillatory versus non-oscillatory palladium(II) iodide-catalysed oxidative carbonylation of phenylacetylene

Lookup NU author(s): Dr Christophe Grosjean, Professor Katarina Novakovic, Dr Mark Willis, Professor Allen Wright

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Abstract

The oxidative carbonylation of phenylacetylene was studied in order to determine the production distribution and reaction conditions which result in oscillatory versus non-oscillatory behaviour. Unambiguous identification of the products and their distribution was undertaken, after which, it was found that reaction conditions which result in oscillatory behaviour produce high conversions, and more selective product distribution.

Publication metadata

Author(s): Grosjean C, Novakovic K, Scott SK, Whiting A, Willis MJ, Wright AR

Publication type: Article

Publication status: Published

Journal: Journal of Molecular Catalysis A: Chemical

Year: 2008

Volume: 284

Issue: 1-2

Pages: 33-39

ISSN (print): 1381-1169

ISSN (electronic): 1873-314X

Publisher: Elsevier BV

URL: http://dx.doi.org/10.1016/j.molcata.2007.12.020

DOI: 10.1016/j.molcata.2007.12.020

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