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Transamination chemistry of sodium TMP-zincate: Synthesis and crystal structure of a chiral amidozincate

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Sophie Dale, Dr Ross Harrington


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In a new type of reactivity for sodium TMP-zincate [(TMEDA)NaZn( tBu)2(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-α-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H). © The Royal Society of Chemistry.

Publication metadata

Author(s): Armstrong DR, Clegg W, Dale SH, Garcia-Alvarez J, Harrington RW, Hevia E, Honeyman GW, Kennedy AR, Mulvey RE, O'Hara CT

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2008

Issue: 2

Pages: 187-189

Print publication date: 01/01/2008

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry


DOI: 10.1039/b713987j


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