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Lookup NU author(s): Emeritus Professor Bill CleggORCiD,
Dr Sophie Dale,
Dr Ross Harrington
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In a new type of reactivity for sodium TMP-zincate [(TMEDA)NaZn( tBu)2(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-α-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H). © The Royal Society of Chemistry.
Author(s): Armstrong DR, Clegg W, Dale SH, Garcia-Alvarez J, Harrington RW, Hevia E, Honeyman GW, Kennedy AR, Mulvey RE, O'Hara CT
Publication type: Article
Publication status: Published
Journal: Chemical Communications
Print publication date: 01/01/2008
ISSN (print): 1359-7345
ISSN (electronic): 1364-548X
Publisher: Royal Society of Chemistry
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