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Electrochemically and photochemically active Palladium(II) heterotopic metallacalix[3]arenes

Lookup NU author(s): Professor Andrew HoultonORCiD, Emeritus Professor Bill CleggORCiD, Dr Ross Harrington


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The cyclic trinuclear system, [(en)3Pd3(4,7-phen) 3]6+, undergoes a ligand exchange reaction with 5-R-2-hydroxypyrimidine derivatives (HRpymo; R = ethynylferrocene, 5-(dimethylamino)-N-(2-propynyl)-1-naphthalene sulfonamide) to give [(en) 3Pd3(4,7-phen)2(Rpymo)]5+, functional supramolecular receptors of mononucleotides. © The Royal Society of Chemistry.

Publication metadata

Author(s): Galindo MA, Houlton A, Clegg W, Harrington RW, Dobado J, Santoyo-Gonzalez F, Linares F, Romero MA, Navarro JAR

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2008

Issue: 32

Pages: 3735-3737

Print publication date: 01/01/2008

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry


DOI: 10.1039/b805705b


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Funder referenceFunder name
Junta de Andalucia and Universidad de Granada
CTQ2005-00329/BQUSpanish Ministry of Science and Education