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Three Pt-II catecholate and 1,2-dithiocatecholate complexes

Lookup NU author(s): Emeritus Professor Bill Clegg

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Abstract

In the crystal structures of the three title complexes, (benzene-1,2-diolato-O,O')bis( triphenylphosphine)platinum(II), [Pt(C6H3O2)(C18H15P)(2)], (1), (benzene-1,2-dithiolato-S,S')bis( triphenylphosphine)platinum(II), [Pt(C6H4S2)(C18H15P)(2)], (2), and the n-hexane hemisolvate of (benzene-1,2-diolato-O,O')bis(tricyclohexylphosphine)platinum(II), [Pt(C6H4O2)(C18H33P)(2)]. 0.5C(6)H(14), (3), the Pt atoms are tetracoordinate with distorted square-planar geometry. Compounds (1) and (2) are isostructural.


Publication metadata

Author(s): Lesley MJG, Clegg W, Marder TB, Norman NC, Orpen AG, Scott AJ, Starbuck J

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica, Section C: Crystal Structure Communications

Year: 1999

Volume: 55

Issue: 8

Pages: 1272-1275

Print publication date: 01/08/1999

ISSN (print): 0108-2701

ISSN (electronic): 1600-5759

Publisher: Wiley-Blackwell Publishing, Inc.

URL: http://dx.doi.org/10.1107/S0108270199005715

DOI: 10.1107/S0108270199005715


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