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Lookup NU author(s): Emeritus Professor Bill Clegg
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Pseudosaccharyl and phenyltetrazolyl derivatives 1-6 were prepared with the aim of weakening the originally strong C-N bond in aromatic amines and facilitating its hydrogenolysis. Structural analyses of the amines 1-6 by H-1 and C-13 NMR spectroscopy and X-ray diffraction methods have revealed major changes in C-N bond lengths on derivatization as a result of changes in conjugation. These changes are discussed in relation to the observed reactivity of compounds 1-6 towards catalytic and non-catalytic C-N bond hydrogenolysis.
Author(s): Brigas AF, Clegg W, Dillon CJ, Fonseca CFC, Johnstone RAW
Publication type: Article
Publication status: Published
Journal: Journal of the Royal Chemical Society: Perkin Transactions 2
ISSN (print): 1472-779X
ISSN (electronic): 1364-5471
Publisher: Royal Society of Chemistry
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