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Lookup NU author(s): Adrain John Dunford,
Professor Richard Henderson
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Substitution of the first chloro-ligand in [Fe4S4Cl4](2-) by 4-RC6H4S- (R = CF3, Cl, H, Me or MeO), in the presence of [H2N(CH2)(3)CH2](+), involves initial binding of thiolate, followed by protonation and finally chloride dissociation; the rate of protonation is facilitated by electron-withdrawing R-substituents indicating that Fe-thiolate bond length changes modulate proton transfer.
Author(s): Dunford AJ, Henderson RA
Publication type: Article
Publication status: Published
Journal: Chemical Communications
ISSN (print): 1359-7345
ISSN (electronic): 1364-548X
Publisher: Royal Society of Chemistry
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