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Chloro-cis-dihydro-mer-tris(triphenylphosphine)-rhodium(III) dichloromethane hemisolvate

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Mark Elsegood


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The title complex, [RhClH2 (C18H15P)(3)] .0.5CH(2)Cl(2), has distorted octahedral coordination of Rh as a consequence of the bulk of the phosphine ligands and the relatively small size of hydride ligands; the latter were not directly located in the crystallographic analysis. The dichloromethane solvent molecule is disordered.

Publication metadata

Author(s): Clegg W, Elsegood MRJ, Norman NC, Pickett NL

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2002

Volume: 58

Issue: part 7

Pages: m406-m407

ISSN (print):

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell Publishing, Inc.


DOI: 10.1107/S1600536802012266


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