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Establishing cleavage conditions for an anthracene chiral auxiliary using a photochemical retro Diels-Alder reaction

Lookup NU author(s): Jonathan Atherton, Dr Simon Jones

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Abstract

Photochemical Diels-Alder additions of chiral 9-anthranyl ethanol derivatives have been conducted giving rise to addition adducts in reasonable yield and excellent diastereoselectivity. Thermal and photochemical retro Diels-Alder additions have also been achieved providing a facile cleavage method for use of this compound Lis a new chiral auxiliary. (C) 2002 Elsevier Science Ltd. All rights reserved.

Publication metadata

Author(s): Atherton JCC, Jones S

Publication type: Article

Publication status: Published

Journal: Tetrahedron Letters

Year: 2002

Volume: 43

Issue: 50

Pages: 9097-9100

ISSN (print): 0040-4039

ISSN (electronic): 1873-3581

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/S0040-4039(02)02255-4

DOI: 10.1016/S0040-4039(02)02255-4

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