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Diastereoselective Diels-Alder reactions of polyether based chiral 9-substituted anthracenes

Lookup NU author(s): Dr Simon Jones

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Abstract

Polyether derivatives of 9-anthryl ethanol undergo highly diastereoselective Diets-Alder additions with maleic anhydride and N-methyl maleimide. Addition of simple cations did not increase reaction rates or change the sense of selectivity through coordinative control induced by binding of the cation to the pendant polyether side-chain.

Publication metadata

Author(s): Jones S, Ojea-Jimenez I

Publication type: Article

Publication status: Published

Journal: Polycyclic Aromatic Compounds

Year: 2005

Volume: 25

Issue: 1

Pages: 1-12

ISSN (print): 1040-6638

ISSN (electronic): 1563-5333

Publisher: Taylor & Francis Inc.

URL: http://dx.doi.org/10.1080/10406630490461646

DOI: 10.1080/10406630490461646

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