Toggle Main Menu Toggle Search

Open Access padlockePrints

N-H center dot center dot center dot S and N-H center dot center dot center dot O hydrogen bonding in tetra-n-butylammonium (imidazolidine-2-thione-2 kappa S)dioxo-1 kappa O-2-di-mu-sulfido-1 : 2 kappa(4) S : S-copper(I) tungstate(VI)

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Sophie Dale


Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


In the title complex, (C16H36N)[WCuO2S2(C3H6N2S)], the W and Cu atoms have tetrahedral and trigonal-planar coordination, respectively. Two sulfide ligands bridge the two metal centres; tungsten is additionally coordinated by two terminal oxo ligands and copper by the exocyclic S atom of imidazolidine-2-thione. There is an intramolecular N-H center dot center dot center dot S hydrogen bond in the anion, and anions are linked into chains by N-H center dot center dot center dot O intermolecular hydrogen bonds. The more loosely held cation is disordered.

Publication metadata

Author(s): Beheshti A, Clegg W, Dale SH, Solimankhani A

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2005

Volume: 61

Issue: 8

Pages: M1509-M1511

ISSN (print):

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell Publishing, Inc.


DOI: 10.1107/S1600536805021628


Altmetrics provided by Altmetric