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N-H center dot center dot center dot S and N-H center dot center dot center dot O hydrogen bonding in tetra-n-butylammonium (imidazolidine-2-thione-2 kappa S)dioxo-1 kappa O-2-di-mu-sulfido-1 : 2 kappa(4) S : S-copper(I) tungstate(VI)

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Sophie Dale

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Abstract

In the title complex, (C16H36N)[WCuO2S2(C3H6N2S)], the W and Cu atoms have tetrahedral and trigonal-planar coordination, respectively. Two sulfide ligands bridge the two metal centres; tungsten is additionally coordinated by two terminal oxo ligands and copper by the exocyclic S atom of imidazolidine-2-thione. There is an intramolecular N-H center dot center dot center dot S hydrogen bond in the anion, and anions are linked into chains by N-H center dot center dot center dot O intermolecular hydrogen bonds. The more loosely held cation is disordered.


Publication metadata

Author(s): Beheshti A, Clegg W, Dale SH, Solimankhani A

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2005

Volume: 61

Issue: 8

Pages: M1509-M1511

ISSN (print):

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell Publishing, Inc.

URL: http://dx.doi.org/10.1107/S1600536805021628

DOI: 10.1107/S1600536805021628


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