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Lookup NU author(s): Professor William Clegg, Dr Sophie Dale
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In the title complex, (C16H36N)[WCuO2S2(C3H6N2S)], the W and Cu atoms have tetrahedral and trigonal-planar coordination, respectively. Two sulfide ligands bridge the two metal centres; tungsten is additionally coordinated by two terminal oxo ligands and copper by the exocyclic S atom of imidazolidine-2-thione. There is an intramolecular N-H center dot center dot center dot S hydrogen bond in the anion, and anions are linked into chains by N-H center dot center dot center dot O intermolecular hydrogen bonds. The more loosely held cation is disordered.
Author(s): Beheshti A, Clegg W, Dale SH, Solimankhani A
Publication type: Article
Publication status: Published
Journal: Acta Crystallographica Section E: Structure Reports Online
Year: 2005
Volume: 61
Issue: 8
Pages: M1509-M1511
ISSN (print):
ISSN (electronic): 1600-5368
Publisher: Wiley-Blackwell Publishing, Inc.
URL: http://dx.doi.org/10.1107/S1600536805021628
DOI: 10.1107/S1600536805021628
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