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'Inverse crown ether' complexes extended to group 12 through the syntheses of [Na2Zn2(HMDS)(4)(O)] and [{K2Zn2(HMDS)(4)(O-2)(x)(O)(y)}(infinity)]

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Stephen Liddle

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Abstract

The first sodium-zinc and potassium-zinc members of the inverse crown ether family, an emerging class of heterometallic macrocyclic amides previously limited to alkali metal-magnesium combinations, have been synthesised and crystallographically characterised.


Publication metadata

Author(s): Forbes GC, Kennedy AR, Mulvey RE, Rowlings RB, Clegg W, Liddle ST, Wilson CC

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2000

Issue: 18

Pages: 1759-1760

Print publication date: 01/01/2000

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/B005233G

DOI: 10.1039/B005233G


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