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First assembly of copper(I) naphthyridine-based helicates

Lookup NU author(s): Emeritus Professor Anthony Harriman

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Abstract

Copper(I) binds to 2,7-diimino-1,8-naphthyridine in solution to form a mixture of equilibrating mono- and polynuclear complexes, as identified by electrospray MS and monitored by UV-visible spectrophotometric titrations, including a binuclear metallo-helicate for which X-ray data are available but whose formation does not require cooperative associations.

Publication metadata

Author(s): Ziessel R, Harriman A, El-ghayoury A, Douce L, Leize E, Nierengarten H, Van Dorsselaer A

Publication type: Article

Publication status: Published

Journal: New Journal of Chemistry

Year: 2000

Volume: 24

Issue: 10

Pages: 729-732

Print publication date: 01/01/2000

ISSN (print): 1144-0546

ISSN (electronic): 1369-9261

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b003342L

DOI: 10.1039/b003342l

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