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Lookup NU author(s): Dr Dominic Paul Seccombe
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A study of the vacuum-ultraviolet (VUV) fluorescence spectroscopy of NF3 in the 11-30 eV range is presented. Synchrotron radiation (SR) from BESSY1, Berlin provides the VUV excitation source. Emission due to NF b(1)Sigma (+) - X (3)Sigma (-) at 528.8 nm is observed between 11.5 and 21.0 eV. Other emissions, which are believed to be due to transitions between highly excited states of NF2, are observed at higher energies, 14.8-24.5 eV. Lifetimes associated with two of these bands at 325 and 410 nm are determined to be 12.9 and 13.0 ns, respectively. The similarity of the measured values implies that the two transitions originate from a common upper state. (C) 2001 Published by Elsevier Science B.V.
Author(s): Seccombe DP, Tuckett RP, Jochims HW, Baumgartel H
Publication type: Article
Publication status: Published
Journal: Chemical Physics Letters
Year: 2001
Volume: 339
Issue: 5-6
Pages: 405-412
ISSN (print): 0009-2614
ISSN (electronic): 1873-4448
Publisher: Elsevier BV
URL: http://dx.doi.org/10.1016/S0009-2614(01)00343-8
DOI: 10.1016/S0009-2614(01)00343-8
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