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Lookup NU author(s): Christopher Hunter,
Professor Richard Jackson
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Copper-catalysed cross coupling of the beta -aminoalkylzinc reagents 1a and 2 with unsaturated alkyl halides gives beta -unsaturated ethylamines in 47-78% yield (4 examples) and enantiomerically pure beta -unsaturated propylamines in 55-69% yield (3 examples). This method is more efficient for simple beta -aminoalkylzinc reagents than that using stoichiometric copper.
Author(s): Hunter C, Jackson RFW, Rami HK
Publication type: Article
Publication status: Published
Journal: Journal of the Royal Chemical Society: Perkin Transactions 1
ISSN (print): 1472-7781
ISSN (electronic): 1364-5463
Publisher: Royal Society of Chemistry
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