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Triple linking of the decaboranyl cluster. Structure of [(SMe2)(2)B10H10(B10H13)(2)] as determined by synchrotron X-ray diffraction analysis

Lookup NU author(s): Emeritus Professor Bill CleggORCiD


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In an attempt to find generic routes to multiple inter-cluster sigma -linking, mild thermolysis of [6,9-(SMe2)(2)-arachno-B10H12] 1 in inert hydrocarbon solution gives the tridecaboranyl species [6,9-(SMe2)(2)-arachno-B10H10-1,5-(6'-nido-B10H13)(2)] 3 (23%).

Publication metadata

Author(s): Bould J, Dorfler U, Clegg W, Teat SJ, Thornton-Pett M, Kennedy JD

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2001

Issue: 18

Pages: 1788-1789

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry


DOI: 10.1039/b105551h


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