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Diaquabis(N,N-diethylnicotinamide)bis(2-hydroxybenzoato)zinc(II)

Lookup NU author(s): Emeritus Professor Bill Clegg

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Abstract

The title compound, [Zn(C7H5O3)(2) (C10H14N2O)(2) (H2O)(2)], crystallizes as centrosymmetric mononuclear molecules with octahedrally coordinated zinc, all pairs of equivalent ligands being mutually trans. Intramolecular hydrogen bonding links each aqua ligand and the hydroxy group of a 2-hydroxybenzoate ligand with the uncoordinated carboxylate O atom of the same carboxylate ligand, lengthening this C-O bond so that it has almost the same length as that for the coordinated O atom. Intermolecular hydrogen bonding between aqua ligands and the carbonyl O atoms of N,N-diethylnicotinamide ligands link the molecules together into chains.


Publication metadata

Author(s): Necefoglu H, Clegg W, Scott AJ

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2001

Volume: 57

Issue: 10

Pages: m462-m464

ISSN (print):

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell Publishing, Inc.

URL: http://dx.doi.org/10.1107/S1600536801015021

DOI: 10.1107/S1600536801015021


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