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Palladium(o) catalysed and copper(I) promoted reactions of the secondary zinc reagent derived from L-threonine

Lookup NU author(s): Ian Wilson, Professor Richard Jackson

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Abstract

C-3 epimeric secondary zinc reagents 2a/b were prepared from either diastereoisomeric iodide 3a or 3b using DMF as solvent, and characterised by H-1 NMR methods. Palladium catalysed cross couplings and copper promoted allylations yielded protected beta-methyl substituted amino acids.

Publication metadata

Author(s): Wilson I, Jackson RFW

Publication type: Article

Publication status: Published

Journal: Journal of the Royal Chemical Society: Perkin Transactions 1

Year: 2002

Issue: 24

Pages: 2845-2850

ISSN (print): 1472-7781

ISSN (electronic): 1364-5463

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b208667k

DOI: 10.1039/b208667k

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