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Synthesis, Structure, and Solution Behavior of a Phosphine-Borane-Stabilized 1,3-Dicarbanion

Lookup NU author(s): Dr Keith Izod, Dr Corinne Wills, Professor William Clegg, Dr Ross Harrington

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Abstract

The reaction between the phosphine-borane{(Me3Si)CH2}(2)P(BH3)Ph (2) and 2 equiv of n-BuLi in THF yields the 1,3-dicarbanion complex (THF)(2)Li{(Me3SiCH)(2)-P(BH3)Ph} Li(THF)(3) (3), which crystallizes as an unusual contact ion pair. In solution 3 is subject to dynamic exchange which interconverts the two lithium environments.

Publication metadata

Author(s): Izod K, Wills C, Clegg W, Harrington RW

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 2010

Volume: 29

Issue: 21

Pages: 4774-4777

Print publication date: 01/11/2010

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om100454t

DOI: 10.1021/om100454t

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