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Browsing publications by Dr Keith Izod.

Newcastle AuthorsTitleYearFull text
Dr Keith Izod
Dr Paul Waddell
Substituent Effects on the Structures of Alkali Metal Phosphido-Borane Complexes2022
Dr Keith Izod
James Watson
Dr Ross Harrington
Emeritus Professor Bill Clegg
Phosphido-bis(borane) complexes of the alkaline earth metals2021
Dr Keith Izod
Dr Paul Waddell
P-Ge/Sn π-Interactions Versus AreneGe/Sn Contacts for the Stabilization of Diphosphatetrylenes, (R2P)2E (E = Ge, Sn)2020
Dr Keith Izod
Peter Evans
Dr Paul Waddell
An Acyclic Arsenium Cation Stabilised by a Single P‐As π‐Interaction and a Cyclic Diphosphinophosphonium Salt2019
Dr Keith Izod
Dr Paul Waddell
Unexpected Activation of Ethers and Polysiloxanes by a Phosphine-Borane-Stabilized 1,3-Dicarbanion/Butyllithium Couple2019
Dr Keith Izod
Peter Evans
Dr Paul Waddell
A diarsagermylene and a diarsastannylene stabilised by arene⋯Ge/Sn interactions2018
Dr Keith Izod
Peter Evans
Emeritus Professor William McFarlane
Dr Paul Waddell
Influence of Chain Length on the Structures and Dynamic Behavior of Alkyl-Tethered alpha,omega-Diphosphide Complexes of Lithium and Their Use in the Synthesis of P-Heterocyclic Stannylenes2018
Dr Keith Izod
Peter Evans
Dr Paul Waddell
A Fully Phosphane-Substituted Disilene2017
Dr Keith Izod
Claire Jones
Dr Ross Harrington
Dr Paul Waddell
A Suite of Sterically-Demanding Hybrid Alkyl/Cyclopentadienyl Ligands2017
Dr Keith Izod
James Watson
Salima El-Hamruni
Dr Ross Harrington
Dr Paul Waddell
et al.
Alkali-metal- and alkaline-earth-metal-mediated C-O activation of an anisole-substituted phosphido-borane ligand2017
Dr Keith Izod
Peter Evans
Dr Paul Waddell
Desolvation and Aggregation of Sterically Demanding Alkali Metal Diarylphosphides2017
Dr Keith Izod
Peter Evans
Dr Paul Waddell
Dr Mike Probert
Remote Substituent Effects on the Structures and Stabilities of P=E π-Stabilized Diphosphatetrylenes (R2P)2E (E = Ge, Sn)2016
Dr Keith Izod
Dr Paul Waddell
Dibenzylstrontium and -barium: Simple Molecules with Complex Structures2015
Dr Keith Izod
Dr Casey Dixon
Dr Ross Harrington
Dr Mike Probert
Impact of a rigid backbone on the structure of an agostically-stabilised dialkylstannylene: isolation of an unusual bridged stannyl–stannylene2015
Dr Keith Izod
Dr Corinne Wills
Salima El-Hamruni
Dr Ross Harrington
Dr Paul Waddell
et al.
Structural Diversity in Alkaline Earth Metal Complexes of a Phosphine-Borane-Stabilized 1,3-Dicarbanion2015
Dr Keith Izod
Dr Corinne Wills
Dr Ross Harrington
Dr Mike Probert
Insights into the stability and structures of phosphine-boranes and their α-metalated derivatives2014
Dr Keith Izod
Salima El-Hamruni
Dr Ross Harrington
Dr Ulrich Baisch
Stabilization of a Diphosphagermylene through pπ-pπ Interactions with a Trigonal-Planar Phosphorus Center2014
Dr Keith Izod
Dr Casey Dixon
Dr Ross Harrington
Dr Ulrich Baisch
Synthesis and Structural Characterization of Phosphine-Borane-Stabilized Dicarbanions with either Rigid or Flexible Spacers2014
Dr Keith Izod
Dr Corinne Wills
Dr Mike Probert
Dr Ross Harrington
Synthesis and structure of an acyclic dialkylstannylene2014
Dr Keith Izod
Dr Ewan Clark
Emeritus Professor Bill Clegg
Dr Ross Harrington
Light-Induced Rearrangement of Thioether-Substituted Phosphanide Ligands: Scope and Limitations of a Remarkable Isomerization2013
Dr Keith Izod
James Watson
Emeritus Professor Bill Clegg
Dr Ross Harrington
Phosphido-Borane and Phosphido-Bis(Borane) Complexes of the Alkali Metals, a Comparative Study2013
Dr Keith Izod
Dr Corinne Wills
Dr Ross Harrington
Emeritus Professor Bill Clegg
Synthesis and structural characterisation of an unusual phosphine-borane-substituted organoplumbate2013
Dr Keith Izod
James Watson
Emeritus Professor Bill Clegg
Dr Ross Harrington
Benzyl Ether-Substituted Phosphido-Borane Complexes of the Alkali Metals2012
Dr Keith Izod
Heavier group 14 complexes with anionic P-donor ligands2012
Dr Keith Izod
Dr Ewan Clark
Emeritus Professor Bill Clegg
Dr Ross Harrington
Hypervalent Sulfur-Functionalized Diphosphagermylene and Diphosphastannylene Compounds2012
Dr Keith Izod
Dr Corinne Wills
Dr Ross Harrington
Emeritus Professor Bill Clegg
Agostically-stabilized dialkylstannylenes and plumbylenes2011
Dr Keith Izod
Dr Ewan Clark
John Stewart
Edge- versus Vertex-Inversion at Trigonal Pyramidal Ge(II) Centers—A New Aromatic Anchimerically Assisted Edge-Inversion Mechanism2011
Dr Keith Izod
Julia Watson
Emeritus Professor Bill Clegg
Dr Ross Harrington
Synthesis, structures and stabilities of thioanisole-functionalised phosphido-borane complexes of the alkali metals2011
Dr Keith Izod
John Stewart
Dr Ewan Clark
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
Germanium(II) and Tin(II) Complexes of a Sterically Demanding Phosphanide Ligand2010
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Ross Harrington
Lanthanide(II) complexes of a phosphine-borane-stabilised carbanion2010
Dr Corinne Wills
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Ross Harrington
Oxidation reactions of a phosphine-borane-stabilised dialkylstannylene2010
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Synthesis, Structure, and Solution Behavior of a Phosphine-Borane-Stabilized 1,3-Dicarbanion2010
Dr Keith Izod
John Stewart
Emeritus Professor Bill Clegg
Dr Ross Harrington
Synthesis, structures and dynamic behavior of intramolecularly base-stabilized diphosphatetrylenes containing a five-membered chelate ring2010
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Acyclic Dialkylstannylene and -Plumbylene Compounds That Are Monomeric in the Solid State2009
Dr Keith Izod
Dr Ewan Clark
Emeritus Professor William McFarlane
Dr Ben Allen
Emeritus Professor Bill Clegg
et al.
Dynamic Behavior of Intramolecularly Base-Stabilized Phosphatetrylenes. Insights into the Inversion Processes of Trigonal Pyramidal Geramanium(II) and Tin(II) Centers2009
Dr Corinne Wills
Dr Keith Izod
Jonathan Young
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
Mixed donor-functionalised phosphinomethanide complexes of the alkali metals; synthesis, structures, and solution dynamics2009
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B-H center dot center dot center dot E Interactions [E = Sn, Pb]2009
Dr Keith Izod
Lyndsey Bowman
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
Synthesis and structural characterisation of alkali metal complexes of heteroatom-stabilised 1,4-and 1,6-dicarbanions2009
Dr Keith Izod
Emeritus Professor William McFarlane
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
Agostic-type B - H⋯Pb interactions stabilize a dialkylplumbylene. Structure of and bonding in [{nPr2P(BH3)}(Me 3Si)C(CH2)]2Pb2008
Dr Keith Izod
John Stewart
Emeritus Professor Bill Clegg
Dr Ross Harrington
Alkali metal complexes of a naphthylamine-substituted phosphanide2008
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Alkali metal complexes of a phosphine-borane-stabilised carbanion: Influence of co-ligands on structure2007
Dr Keith Izod
John Stewart
Emeritus Professor Bill Clegg
Dr Ross Harrington
Alkali metal complexes of sterically demanding amino-functionalised secondary phosphanide ligands2007
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Alkaline earth metal complexes of a phosphine-borane-stabilized carbanion: Synthesis, structures, and stabilities2007
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Influence of aromatic ring substituents and co-ligand on the binding mode of a phosphine-borane-stabilized carbanion; crystal structures of [[(Me3Si)2{Ph2P(BH3)}C]KLn]2[Ln = (OEt2)2, pmdeta; pmdeta = N,N,N′,N″,N″-pentamethyldiethylenetriamine]2007
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Metalation of trimethylphosphine-borane. Unexpected reactivity of a simple phosphine-borane-stabilized carbanion toward siloxanes2007
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Ross Harrington
Synthesis and structures of Ln(II) and Ln(III) dialkyls derived from LnI2 (Ln = Nd, Tm, Yb)2007
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Ross Harrington
σ-Bonded organometallic derivatives of yttrium(III) and thulium(III): An unusual ligand coupling reaction mediated by thulium(III)2007
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Ross Harrington
Alkali metal complexes of sterically hindered mono- and di-carbanions containing Si-O bonds2006
Dr Keith Izod
Dr Stephen Liddle
Emeritus Professor Bill Clegg
Dr Ross Harrington
Amino-functionalised diarylphosphide complexes of the alkali metals and lanthanum2006
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Heavier alkali metal complexes of a silicon- and phosphine-borane- stabilized carbanion2006
Lyndsey Bowman
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Ross Harrington
Heteroleptic complexes of lanthanum(III) and neodymium(III) with oxygen- or nitrogen-functionalized tris(triorganosilyl)methyl ligands2006
Dr Keith Izod
Emeritus Professor William McFarlane
Brent Tyson
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
Stabilization of a dialkylstannylene by unusual B-H⋯Sn γ-agostic-type interactions. A structural, spectroscopic, and DFT study2006
Dr Stephen Liddle
Dr Keith Izod
Synthesis and crystal structure of the heteroleptic lanthanum(III) bis-diphosphinomethanide complex [La{CH(PPh2)2}2(I)(THF)2]2006
Dr Keith Izod
Dr Corinne Wills
Emeritus Professor Bill Clegg
Dr Ross Harrington
Synthesis, crystal structure, and solution behavior of a sterically hindered α-metalated phosphine-borane2006
Dr Keith Izod
Emeritus Professor William McFarlane
Dr Ben Allen
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
An intramolecularly base-stabilized diphosphagermylene and two unusual germanium(II) ate complexes: A structural, NMR, and DFT study2005
Dr Keith Izod
Jonathan Young
Emeritus Professor Bill Clegg
Dr Ross Harrington
Effect of peripheral donor substituents on the binding modes of phosphinomethanide ligands. Synthesis and crystal structures of alkali metal derivatives of an O-functionalised phosphinomethanide ligand2005
Dr Keith Izod
The germanium(II) ate complex [Ph3PiPr][Ge(OCOMe) 3]: The first structurally characterized compound containing a discrete [E14(II)O3](-) (E14(II) = Si, Ge, Sn or Pb) anion2005
Dr Keith Izod
Dr Stephen Liddle
Emeritus Professor Bill Clegg
A Convenient Route to Lanthanide Triiodide THF Solvates. Crystal Structures of Lnl3(THF)4 [Ln = Pr] and Lnl 3(THF)3.5 [Ln = Nd, Gd, Y]2004
Dr Keith Izod
Emeritus Professor William McFarlane
Brent Tyson
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
Complexes of a dianionic bis(diphosphinomethanide) with lithium, sodium, potassium and zirconium. Effect of substitution on the Schlenk dimerisation of vinylidene phosphines2004
Stuart Blair
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Ross Harrington
Complexes of the heavier alkaline earth metals Ca, Sr, and Ba with O-functionalized phosphanide ligands2004
Dr Keith Izod
Dr Stephen Liddle
Emeritus Professor Bill Clegg
Protonation of a lanthanum phosphide-alkyl occurs at the P-La not the C-La bond: Isolation of a cationic lanthanum alkyl complex2004
Dr Keith Izod
Emeritus Professor William McFarlane
Brent Tyson
Scope and limitations of the Peterson olefination reaction as a route to vinylidene phosphanes2004
Dr Stephen Liddle
Dr Keith Izod
Synthesis and characterization of 1,3-diphosphapropene and alkali-metal 1,3-diphosphaallyl complexes and unexpected 1,3-rearrangement of a cesium 1,3-diphosphaallyl complex to a cesium secondary phosphanide2004
Dr Keith Izod
Dr Stephen Liddle
Emeritus Professor William McFarlane
Emeritus Professor Bill Clegg
Synthesis and reactions of sterically encumbered, heteroleptic lanthanum phosphides. Structural characterization of [{(Me3Si)2CH}-(C6H4-2-Ch2NMe 2)P]2La(OR) and [{(Me3Si)2CH}- (C6)H4-2-CH2NMe2)P]La(THF)[P(C6H4-2-CH2NMe2)-{CH(SiMe 3)(SiMe2CH2)}] [R =i-Pr, t-Bu]2004
Dr Keith Izod
Dr Stephen Liddle
Emeritus Professor William McFarlane
Emeritus Professor Bill Clegg
Synthesis and Reactions of Sterically Encumbered, Heteroleptic Lanthanum Phosphides. Structural Characterization of [{(Me3Si)2CH}-(C6H4-2-CH2NMe2)P]2La(OR) and [{(Me3Si)2CH}- (C6H4-2-CH2NMe2)P]La(THF)[P(C6H4-2-CH2NMe2)-{CH(SiMe3)(SiMe2CH2)}] [R = i-Pr, t-Bu]2004
Dr Keith Izod
Emeritus Professor William McFarlane
Brent Tyson
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
Synthesis and structural characterisation of a novel phosphine-borane- stabilised dicarbanion and an unusual bis(phosphine-borane)2004
Dr Keith Izod
Emeritus Professor William McFarlane
Brent Tyson
Emeritus Professor Bill Clegg
Dr Ross Harrington
et al.
Alkali Metal-Mediated Schlenk Dimerization of a Phosphorus-Substituted Alkene. Synthesis and Crystal Structures of Li, Na, and K Derivatives of a Phosphorus-Stabilized Butane-l,4-diide Ligand2003
Dr Keith Izod
Dr Stephen Liddle
Emeritus Professor Bill Clegg
Alkyl complexes of strontium and barium: Synthesis and structural characterization of {(Me3Si)2(MeOMe2Si)C}2Sr(THF) and {(Me3Si)2(MeOMe2Si)C}2Ba (MeOCH2CH2OMe)2003
Dr Keith Izod
Emeritus Professor Bill Clegg
C2-Symmetric ytterbium(II) complexes with a novel, chiral P,N-donor ligand2003
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Ross Harrington
Organomagnesium phosphanide "grignard" analogues - Synthesis, structural characterisation and solution behaviour of [BuMg{P(CH[SiMe 3]2)(C6H3-2-OMe-3R)}]2 [R = H, Me]2003
Dr Keith Izod
Dr Ross Harrington
Emeritus Professor Bill Clegg
Sterically controlled mono- or dimetalation of a thioether-functionalized phosphine and an unusual light-induced phosphide-thiolate rearrangement2003
Dr Stephen Liddle
Dr Keith Izod
The first structurally authenticated alkali metal 1,3-diphosphaallyl complex [{ButC(PMes)2}Li(thf)3] (Mes = 2,4,6-Me3C6H2): An alternative synthetic approach to substituted 1,3-diphosphaallyl complexes2003
Stuart Blair
Dr Keith Izod
Emeritus Professor Bill Clegg
A homologous series of alkaline earth phosphanides: Syntheses, crystal structures, and unusual dynamic behavior of (THF),nM[P{CH(Si-Me3)2} (C6H4-2-CH2NMe2)]2 (M = Mg, Ca, Sr, Ba)2002
Dr Keith Izod
Emeritus Professor Bill Clegg
A Homologous Series of Alkaline Earth Phosphanides: Syntheses, Crystal Structures, and Unusual Dynamic Behavior of (THF)nM[P{CH(Si- Me3)2}(C6H4-2-CH2NMe2)]2 (M = Mg, Ca, Sr, Ba)2002
Dr Keith Izod
A new era in divalent organolanthanide chemistry?2002
Dr Keith Izod
A new era in divalent organolanthanide chemistry?2002
Dr Keith Izod
Complexes of P-stabilised carbanions with s- and p-elements2002
Dr Keith Izod
Emeritus Professor William McFarlane
Emeritus Professor Bill Clegg
Dilithio-1,1,2-tris(diphenylphosphinoyl)ethane-1,2-diide: The first formal 1,2-dicarbanion stabilised by phosphorus?2002
Dr Keith Izod
Emeritus Professor Bill Clegg
Isolation and structural characterisation of two sterically crowded diphosphanes2002
Dr Keith Izod
Paul O'Shaughnessy
Emeritus Professor Bill Clegg
Unusual solvent-promoted smiles rearrangement of two different phosphorus-containing organolithium compounds to the same lithium phosphide. Crystal structure of MeP{C6H4-2-CH(C6H4-2-CH2N Me2)NMe2}Li(THF)22002
Dr Keith Izod
Paul O'Shaughnessy
Emeritus Professor Bill Clegg
Dr Stephen Liddle
Regioselective metalation of a tertiary phosphine. Synthesis and structural characterization of an unusual tetramerie lithium phosphinomethanide2001
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Stephen Liddle
The first structurally authenticated Rb-PR3 and Cs-PR3 contacts. Synthesis and crystal structures of [Rb{(Me3Si)2CP(C6H4-2-CH2 NMe2)2}]n and [Cs{(Me3Si)2CP(C6H4-2-CH2 NMe2)2}(toluene)]n2001
Dr Keith Izod
Group I complexes of P- and as-donor ligands2000
Emeritus Professor Bill Clegg
Dr Keith Izod
Paul O'Shaughnessy
Manganese and cesium derivatives of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C. Crystal structures of Li(THF)2.75(Et2O)0.25(μ-Cl)-MnC(SiMe 3)2SiMe2CH2CH2Me 2Si(Me3Si)2C2000
Emeritus Professor Bill Clegg
Dr Keith Izod
Paul O'Shaughnessy
Manganese and Cesium Derivatives of the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal Structures of Li(THF)2.75(Et2O)0.25(μ-Cl)- MnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C and (C6H6)3CsC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CCs(C6H6)32000
Dr Keith Izod
Emeritus Professor Bill Clegg
Dr Stephen Liddle
Parallels between the chemistry of alkoxo-phosphidecalcium(II) and ytterbium(II). Synthesis and crystal structure of a calcium alkoxo-phosphide cuboidal complex2000
Emeritus Professor Bill Clegg
Dr Keith Izod
Dr Stephen Liddle
Synthesis and crystal structure of a homoleptic, alkali metal-free lanthanide(II) phosphide complex2000
Dr Keith Izod
Paul O'Shaughnessy
Dr Joanne Sheffield
Emeritus Professor Bill Clegg
Dr Stephen Liddle
et al.
Synthesis and structural characterization of Sm(II) and Yb(II) complexes containing sterically demanding, chelating secondary phosphide ligands2000
Emeritus Professor Bill Clegg
Dr Keith Izod
Dr Stephen Liddle
Paul O'Shaughnessy
Dr Joanne Sheffield
et al.
Synthesis and structural characterization of the first lanthanide(II) cuboidal cluster. Unexpected C-O activation by an unchanged ytterbium(II) center2000
Dr Maurice Hill
Dr Keith Izod
Paul O'Shaughnessy
Emeritus Professor Bill Clegg
Synthesis, structures, and solution dynamics of functionalized phosphinomethanide complexes of the alkali metals2000
Emeritus Professor Bill Clegg
Dr Keith Izod
Paul O'Shaughnessy
First structurally authenticated heavier alkali metal phosphinomethanide1999
Emeritus Professor Bill Clegg
Dr Simon Doherty
Dr Keith Izod
Paul O'Shaughnessy
Dr Joanne Sheffield
et al.
Monomeric alkali metal complexes of a sterically demanding, donor-functionalised secondary phosphide ligand1999
Emeritus Professor Bill Clegg
Dr Keith Izod
Emeritus Professor William McFarlane
Paul O'Shaughnessy
Regioselective metalation of a tertiary phosphine. Solution and solid-state structures of an unusual aminobenzyllithium complex1999
Emeritus Professor Bill Clegg
Dr Keith Izod
Paul O'Shaughnessy
Tris(triorganosilyl)methyl derivatives of potassium and lithium bearing dimethylamino or methoxy substituents at silicon. Crystal structures of KC(SiMe3)2(SiMe2NMe2), KC(SiMe2NMe2)3 and [LiC(SiMe3)(SiMe2OMe)2]21999