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Lookup NU author(s): Dr James KnightORCiD
This is the authors' accepted manuscript of an article that has been published in its final definitive form by Royal Society of Chemistry, 2016.
For re-use rights please refer to the publisher's terms and conditions.
© The Royal Society of Chemistry 2016.The co-ordination chemistry of a tristhiourea tris(2-pyridylmethyl)amine ligand (L1) with a series of transition metal ions has been investigated. Crystallographic data show that large metal ions, with no geometrical preferences, such as Mn(ii) and Cd(ii), will form seven co-ordinate monocapped octahedral complexes, while smaller metal ions such as Zn(ii) favour five co-ordinate trigonal bipyramidal structures. In a similar manner to the related bisthiourea complexes, the Ni(ii) complex shows a strong preference for octahedral geometries resulting in the ligand binding asymmetrically. Spectroscopic (IR and NMR), spectrometric (MS) as well as electrochemical data for these complexes are reported.
Author(s): Saad FA, Knight JC, Kariuki BM, Amoroso AJ
Publication type: Article
Publication status: Published
Journal: Dalton Transactions
Print publication date: 07/07/2016
Online publication date: 23/05/2016
Acceptance date: 19/05/2016
Date deposited: 30/08/2018
ISSN (print): 1477-9226
ISSN (electronic): 1477-9234
Publisher: Royal Society of Chemistry
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