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Lookup NU author(s): Professor David XieORCiD
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (CC BY-NC-ND).
The photooxidative stability of an aromatic segmented poly(urethane-urea) (PUU) elastomer, stabilised with a range of carbon black fillers, was assessed after very low UVA doses as a means to identify components that are highly susceptible to UV degradation, and suggest better design of such materials. Fourier-transform infrared (FTIR) analysis indicated rapid degradation of the urea bonds in the hard segments, followed by chain scission and photo-Fries reaction of the urethane linkages. In the soft segments, the oxidation of the original ether groups resulted in the formation of large amounts of ester groups, while some crosslinking of the ether groups was also evident. Carbon black provided moderate protection against degradation, with the smallest-sized particles being the most effective. Protection was evidenced by reduced surface cracking as well as an increased resistance to chemical changes in both the soft segments and hard segments. Even so, significant degradation was still evident at low UV doses suggesting that further stabilisation is required to increase the UV durability of these elastomers and improve their long-term performance.
Author(s): Zhang T, Xie F, Motuzas J, Bryant P, Kurusingal V, Colwell JM, Laycock B
Publication type: Article
Publication status: Published
Journal: Polymer Degradation and Stability
Year: 2018
Volume: 157
Pages: 181-198
Print publication date: 01/11/2018
Online publication date: 06/09/2018
Acceptance date: 05/09/2018
Date deposited: 23/05/2023
ISSN (print): 0141-3910
ISSN (electronic): 1873-2321
Publisher: Elsevier
URL: https://doi.org/10.1016/j.polymdegradstab.2018.09.020
DOI: 10.1016/j.polymdegradstab.2018.09.020
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