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Structure, thermal stability and suspension rheological properties of alcohol–alkali-treated waxy rice starch

Lookup NU author(s): Professor David XieORCiD

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This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (CC BY-NC-ND).


Abstract

In this work, the effect of alcoholic-alkaline treatment on the characteristics of waxy rice starch (WRS) and its aqueous suspensions was studied for the first time. Microscopy shows that the alcohol-alkali-treated WRS (AAT-WRS) was in the form of particles of lengths between 10 and 50 μm. Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analyses indicate that the original A-type crystallites of WRS had been completely eliminated by the alcoholic-alkaline treatment and no new crystalline structure was formed. Fourier-transform infrared (FTIR) spectroscopy confirms the absence of chemical reactions during the treatment. Thermogravimetric analysis (TGA) results indicated the decreased thermal stability of AAT-WRS, which may be attributed to the amorphous structure and possible degradation resulting from the treatment. Compared with the gelatinized starch suspension, the AAT-WRS aqueous suspension presented a weaker shear-thinning behaviour, lower steady-shear viscosity, lower storage and loss moduli, and higher loss tangent, which suggest a less-rigid gel structure. The rigidity of the gel further decreased with higher temperatures. Our results here could provide insights into the rational design of modified starch products with waxy rice starch.


Publication metadata

Author(s): Chen F, Xie F, Liu P, Chen P

Publication type: Article

Publication status: Published

Journal: International Journal of Biological Macromolecules

Year: 2019

Volume: 134

Pages: 397-404

Print publication date: 01/08/2019

Online publication date: 04/05/2019

Acceptance date: 03/05/2019

Date deposited: 31/08/2023

ISSN (print): 0141-8130

ISSN (electronic): 1879-0003

Publisher: Elsevier

URL: https://doi.org/10.1016/j.ijbiomac.2019.05.009

DOI: 10.1016/j.ijbiomac.2019.05.009


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Funding

Funder referenceFunder name
201610010019
2018A0303130048
798225
2017M612679
2017YT05H077
China Postdoctoral Science Foundation
European Union Horizon 2020
Guangxi Key Laboratory of Polysaccharide Materials and Modification, Guangxi University for Nationalities
GXPSMM18ZD-02
Natural Science Foundation of Guangdong Province
Pearl River S and T Nova Program of Guangzhou
Sailing Scheme of Guangdong Province

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