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First structurally authenticated heavier alkali metal phosphinomethanide

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Keith Izod, Paul O'Shaughnessy

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Abstract

Metathesis between Li[C(SiMe3)2{P(C6H4-2-CH 2NMe2)2}] (1) and KO-t-Bu yields [{K[C(SiMe3)2-{P(C6H4-2-CH 2NMe2)2}]}2]∞ (2), the first heavier alkali metal complex of a phosphorus-stabilized carbanion to be structurally characterized.


Publication metadata

Author(s): Clegg W, Izod K, O'Shaughnessy P

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 1999

Volume: 18

Issue: 16

Pages: 2939-2940

Print publication date: 02/08/1999

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om990276j

DOI: 10.1021/om990276j


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