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Regioselective metalation of a tertiary phosphine. Solution and solid-state structures of an unusual aminobenzyllithium complex

Lookup NU author(s): Professor William Clegg, Dr Keith IzodORCiD, Emeritus Professor William McFarlane, Paul O'Shaughnessy

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Abstract

Metalation of the tertiary phosphine MeP-(C6H4-2-CH2NMe2)2 with t-BuLi proceeds exclusively to give the novel dimeric benzyllithium complex [MeP(C6H4-2-CH2NMe2){C 6H4-2-CH(Li)NMe2}]2; variable-temperature NMR studies show that this complex undergoes a novel dynamic process in solution.

Publication metadata

Author(s): Clegg W, Izod K, McFarlane W, O'Shaughnessy P

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 1999

Volume: 18

Issue: 20

Pages: 3950-3952

Print publication date: 27/09/1999

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om9904910

DOI: 10.1021/om9904910

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