Toggle Main Menu Toggle Search

Open Access padlockePrints

Regioselective metalation of a tertiary phosphine. Solution and solid-state structures of an unusual aminobenzyllithium complex

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Keith Izod, Emeritus Professor William McFarlane, Paul O'Shaughnessy


Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Metalation of the tertiary phosphine MeP-(C6H4-2-CH2NMe2)2 with t-BuLi proceeds exclusively to give the novel dimeric benzyllithium complex [MeP(C6H4-2-CH2NMe2){C 6H4-2-CH(Li)NMe2}]2; variable-temperature NMR studies show that this complex undergoes a novel dynamic process in solution.

Publication metadata

Author(s): Clegg W, Izod K, McFarlane W, O'Shaughnessy P

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 1999

Volume: 18

Issue: 20

Pages: 3950-3952

Print publication date: 27/09/1999

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society


DOI: 10.1021/om9904910


Altmetrics provided by Altmetric