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Synthesis, structures, and solution dynamics of functionalized phosphinomethanide complexes of the alkali metals

Lookup NU author(s): Dr Maurice Hill, Dr Keith Izod, Paul O'Shaughnessy, Emeritus Professor Bill Clegg

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Abstract

Metathesis between [Li{(Me3Si)2C}P(C6 H4-2-CH2NMe2)2] and NaOBut in ether yields the sodium phosphinomethanide [Na{(Me3Si)2C}P(C6 H4-2-CH2NMe2)2(Et2O)0.5(DME)0.5] (2b) after recrystallization. Complex 2b and its Li and K analogues are highly fluxional in solution, and the dynamic processes accounting for this have been studied by variable-temperature 1H NMR spectroscopy.


Publication metadata

Author(s): Stuart Hill MN, Izod K, O'Shaughnessy P, Clegg W

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 2000

Volume: 19

Issue: 22

Pages: 4531-4535

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om000447g

DOI: 10.1021/om000447g


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