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Parallels between the chemistry of alkoxo-phosphidecalcium(II) and ytterbium(II). Synthesis and crystal structure of a calcium alkoxo-phosphide cuboidal complex

Lookup NU author(s): Dr Keith Izod, Emeritus Professor Bill Clegg, Dr Stephen Liddle

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Abstract

Metathesis between CaI2 and K[P{CH(SiMe3)2}(C6H4-2-OMe)] in THF yields the alkoxophosphide complex [Ca{P(CH[SiMe3]2)(C6H 4-2-O)}(THF)]4·4THF (2) via a ligand cleavage reaction involving the migration of a methyl group from oxygen to phosphorus. X-ray crystallography shows that 2 contains a Ca4O4 cuboidal core with μ2-phosphide groups bridging four of the faces of the cuboid. © 2000 American Chemical Society.


Publication metadata

Author(s): Izod K, Clegg W, Liddle ST

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 2000

Volume: 19

Issue: 18

Pages: 3640-3643

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om000357b

DOI: 10.1021/om000357b


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